The methodology of the approximation and interpretation of thermal desorption spectra (TDS) of hydrogen in some carbon nanostructures and graphite has been developed and applied for such materials.
The methodology is based on a definite approximation by the symmetrical Gaussians of the hydrogen thermal desorption spectra, obtained by using one single heating rate, for carbon materials and nanomaterials, and a definite processing of the Gaussians, in the approximation of the first-order reactions and the second-order ones. It results in determining (with a satisfactory accuracy, for the further physical analysis), from TDS data of one single heating rate, the activation energies and pre-exponential factors of the rate constants of desorption processes corresponding to the main TDS peaks with different temperatures of the maximum desorption rate. The developed methodology contains several successive steps of its implementation, including the use of several “criterions of truth” and the final verification and/or modification of the results, with the help of numerical modeling methods. This technique is not less informative, but much less time-consuming in experimental terms compared to the generally accepted classical Kissinger method, which demands using of several heating rates, and has strict limits of applicability. Furthermore, the methodology allows one to reveal physics and atomic mechanisms of the main desorption processes through thermodynamic analysis of the obtained peak characteristics and comparison with the corresponding independent experimental and theoretical data.
The purpose of such a methodology is to further reveal the weakly studied physics of the main states of hydrogen in carbon materials and nanomaterials, and not the thorough detailed mathematical description of the spectra. For this case, both the large difference and the large spread of the known experimental and theoretical values of the thermodynamic characteristics of the main desorption processes, important for hydrogen storage problems, are also taken into account.
Background:
Glaucoma, a characteristic type of optic nerve degeneration in the posterior pole of the eye, is a common cause of irreversible vision loss and the second leading cause of blindness worldwide. As an optic neuropathy, glaucoma is identified by increasing degeneration of retinal ganglion cells (RGCs), with consequential vision loss. Current treatments only postpone the development of retinal degeneration, and there are as yet no treatments available for this disability. Recent studies have shown that replacing lost or damaged RGCs with healthy RGCs or RGC precursors, supported by appropriately designed bio-material scaffolds, could facilitate the development and enhancement of connections to ganglion cells and optic nerve axons. The consequence may be an improved retinal regeneration. This technique could also offer the possibility for retinal regeneration in treating other forms of optic nerve ailments through RGC replacement.
Methods:
In this brief review, we describe the innovations and recent developments in retinal regenerative medicine such as retinal organoids and gene therapy which are specific to glaucoma treatment and focus on the selection of appropriate bio-engineering principles, biomaterials and cell therapies that are presently employed in this growing research area.
Results:
Identification of optimal sources of cells, improving cell survival, functional integration upon transplantation, and developing techniques to deliver cells into the retinal space without provoking immune responses are the main challenges in retinal cell replacement therapies.
Conclusion:
The restoration of visual function in glaucoma patients by the RGC replacement therapies requires appropriate protocols and biotechnology methods. Tissue-engineered scaffolds, the generation of retinal organoids, and gene therapy may help to overcome some of the challenges in the generation of clinically safe RGCs.
Additive manufacturing offers unique possibilities to produce complex components, which would not be possible or only very difficult to be realizable with conventional manufacturing processes. The potential of additive manufacturing of aluminum alloys has already been realized in prototyping, but still offers potential in the establishment of series applications. For enabling the establishment of additive manufacturing in series applications, comprehensive knowledge about the material behavior is necessary. This study examines the torsional behavior of additive manufactured AlSi10Mg samples and shows the correlation between tensile and torsional strength. Comprehensive torsion tests with strain gauges were performed and significant directional dependencies were shown. The correlation factor in the area of torsional yield strength/tensile yield strength and torsional strength/tensile strength was determined and was compared with the yield/failure conditions according to Tresca and von Mises.
Herein, the general constitutive equation of bi-phasic materials equipped with orientation tensor is presented in direct notation. The formulation is refined by some correction factors specific to natural fibre-reinforced composites; then, a planar case is derived. The necessity of local information is emphasised through the introduction of auxiliary maps, which included volume fraction and orientation data. A semi-analytical homogenisation method is introduced through finite element analysis. Auxiliary maps are shown to be a better alternative to the overall orientation of fibres. Global calculations are insensitive to local variations whilst appropriate auxiliary maps offer refined results. Considering the multidisciplinary application of orientation tensors, the proposed scheme can be used in all areas where local information cannot be disregarded.
Laser powder-bed fusion has become one of the most important techniques in additive manufacturing. For guaranteeing the possibility of manufacturing highly specialized and advanced components, currently intensive research is carried out in this field. One area of this research is the material-specific macroscopic anisotropy, which is investigated in our work by comprehensive static mechanical experiments. The material which was tested within this study was the precipitation-hardenable AlSi10Mg alloy, with the focus on installation space orientation. Tensile and compression tests were performed, the results for the Young's modulus in compressive loading exceeded the previously known values of this material in tensile loading and achieved values of up to 79.8 GPa. As a result of this investigation, a chemical spectroscopic analysis was undertaken and from the actual chemical composition, a relative density of 99.86% of the samples was determined.
Laser powder bed fusion has become one of the major techniques within metal additive manufacturing, especially when delicate structures and high geometric accuracy are concerned. Lately, the awareness of the material-specific macroscopic anisotropy has risen and led to widespread investigations on the static mechanical strength. However, little is known about the fracture behavior of the layer-wise fabricated metal components and their affinity of crack propagation between consecutive layers, which is particularly important for aluminium–silicon alloys containing embrittled zones in double-irradiated areas. A recent study indicated that there is a significant drop in fracture toughness in case the crack growth direction is parallel to the layering. To investigate this matter further and to shed light on the fracture toughness behavior in the range of a 0°–45° angle offset between the crack growth direction relative to the layering, notched samples with varying polar angles were subjected to mode I fracture toughness testing. Our results indicate that the fracture toughness is an almost-stable characteristic up to a mismatch of about 20° between the crack propagation path and the layering, at which point the fracture toughness decreases by up to 10%.
Metal additive manufacturing of dental prostheses consisting of cobalt−chromium−tungsten (Co−Cr−W) alloys poses an alternative to investment casting. However, metal additive manufacturing processes like Laser Powder‐Bed Fusion (LPBF) can impact the elastic constants and the mechanical anisotropy of the resulting material. To investigate the phase compositions of mechanically different specimens in dependence of their postprocessing steps (e. g. heat treatment to relieve stress), the current study uses X‐ray Diffraction (XRD), Electron BackScatter Diffraction (EBSD), and Transmission Electron Microscopy (TEM) for phase identification. Our studies connect plastic deformation of Remanium star CL alloy with the formation of the hexagonal ϵ‐phase and heat treatment with the formation of the D024‐phase, while partially explaining previously observed differences in Young's moduli.
The characteristics and atomic mechanisms (physics) of processes of thermal desorption of deuterium from isotropic graphite at temperatures 700–1700 K are considered.
Development of environment-friendly natural fiber composites has been a recent trend. However, due to the fact that natural fibers permit high level of moisture absorption from the surroundings, it can lead to weak bindings and degradation of composite properties. This paper presents an experimental study on the dynamic performance of flax fiber composite beams manufactured at different relative humidity (RH) levels. Five types of flax fiber-reinforced composite materials were made under different RH values, i.e., dry, 35%, 50%, 70%, and 95% RH, and beam samples were prepared using the composite. Impact hammer testing was conducted to measure the natural frequencies and damping of the beams. It was found that for the first three modes, while the resonant frequencies are very close for most samples, there is a clear drop of frequencies for the composite fabricated at 95% RH. Along with an increase of the RH level, the damping ratios for all the three modes have reported a slight increase, but the variation is not significant.
Das Interesse der Industrie an additiv gefertigten Bauteilen steigt z unehmend, wobei mit zunehmendem Verständnis der statischen Kennwerte nunmehr der Fokus in Richtung der dynamischen Festigkeiten wandert. Deswegen werden Einflussparameter auf die Lebensdauer und potenzielle Nachbearbeitungsmethoden untersucht und analysiert. Ein großer Einfluss ist dabei der Oberflächengüte und den durch Rautiefen initiierten Kerbeffekten zuzuschreiben. Deswegen werden unterschiedliche Methoden zur Verbesserung der Oberflächengüte untersucht. Dabei werden die Verfahren Laserpolieren, elektrochemisches Polieren und Hartmetallkugelstrahlen und deren Auswirkung auf Oberflächengüte sowie Härte untersucht. Für das elektrochemische Polieren werden die Proben in einer Perchlorsäure für 90 s bei 32 V und maximal 10 A poliert. Das Hartmetallkugelstrahlen wird mit einem UFS 100 Strahlmittel bei einem Druck von 4 bar und einer Strahldauer von 10 s ausgeführt. Anschließend werden Wöhlerlinien für die unterschiedlichen Zustände mittels Umlaufbiegeversuch ermittelt, welche mit Referenzwerten analysierter konventioneller Proben verglichen werden. Des Weiteren werden die Bruchflächen analysiert. Die Untersuchungen ergaben ein hohes Optimierungspotenzial der additiv gefertigten Proben bei einer Verdichtung der Oberfläche sowie einer Entfernung der Randschicht durch eine spanende Bearbeitung. Dadurch wurden höhere Zeitfestigkeiten als mit konventionell gefertigten Proben erreicht.