TY - JOUR U1 - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed) A1 - Simolka, Matthias A1 - Kaess, Hanno A1 - Friedrich, Kaspar Andreas T1 - Comparison of fresh and aged lithium iron phosphate cathodes using a tailored electrochemical strain microscopy technique JF - Beilstein Journal of Nanotechnology N2 - Electrochemical strain microscopy (ESM) is a powerful atomic force microscopy (AFM) mode for the investigation of ion dynamics and activities in energy storage materials. Here we compare the changes in commercial LiFePO4 cathodes due to ageing and its influence on the measured ESM signal. Additionally, the ESM signal dynamics are analysed to generate characteristic time constants of the diffusion process, induced by a dc-voltage pulse, which changes the ionic concentration in the material volume under the AFM tip. The ageing of the cathode is found to be governed by a decrease of the electrochemical activity and the loss of available lithium for cycling, which can be stored in the cathode. KW - Elektrochemie KW - Lithium-Eisensulfid-Batterie Y1 - 2020 U6 - https://doi.org/https://doi.org/10.3762/bjnano.11.46 DO - https://doi.org/https://doi.org/10.3762/bjnano.11.46 VL - 11 SP - 583 EP - 596 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften CY - Frankfurt am Main ER -